MATERIAL SAFETY DATA SHEET
MSDS 0262
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Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
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HMIS CODES
PRODUCT NAME Health 3
8-Way Flammability 0
Reactivity 1
PRODUCT CODES PPI D
68712, 68714, 68716
CHEMICAL FAMILY
Inorganic Base
USE
Boiler Water Treatment
MANUFACTURER'S NAME EMERGENCY TELEPHONE NO.
The RectorSeal Corporation Chemtrec 24 Hours
2601 Spenwick Drive (800) 424-9300
Houston, Texas 77055 USA
VALIDATION DATE TECHNICAL SERVICE TELEPHONE NO.
February 21, 2006 (800) 231-3345
REVISION DATE
February 21, 2006
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Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
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% by WT CAS No. INGREDIENT UNITS
4.87 68915-31-1 Sodium Phosphate
ACGIH TLV N/D
OSHA PEL N/D
3.21 1310-73-2 Sodium Hydroxide
ACGIH TLV CL 2 mg/m3
OSHA PEL CL 2 mg/m3
6.78 1312-76-1 Sodium Nitrite
ACGIH TLV N/D
OSHA PEL N/D
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Section 3 -- HAZARDS IDENTIFICATION
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SUMMARY OF ACUTE HAZARDS
Exposure to human tissue will result in irritation and chemical burns.
ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS
INHALATION
Extremely corrosive to respiratory system.
EYE CONTACT
Corrosive, contact causes severe eye burns.
SKIN CONTACT
Corrosive to skin.
INGESTION
Poison! Swallowing large quantities can cause death and burns to digestive
system.
SUMMARY OF CHRONIC HAZARDS
Exposure to human tissue will result in irritation and chemical burns.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Individuals with pre-existing or chronic diseases of the eyes, skin
or persons with chemical sensitivity may have increased susceptibility to
excessive exposures.
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Section 4 -- FIRST AID MEASURES
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If INHALED: If overcome by exposure, remove victim to fresh air
immediately. Give oxygen or artificial respiration as
needed. Obtain emergency medical attention. Prompt action
is essential.
If on SKIN: Flush with large amounts of water. If irritation or burns
occur, seek immediate medical attention.
If in EYES: Flush with large amounts of water for at least 15 minutes.
Get medical attention if irritation persists.
If SWALLOWED: If swallowed, call a physician immediately. Only induce
vomiting at the instruction of a physician. Never give
anything by mouth to an unconscious person.
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Section 5 -- FIRE FIGHTING MEASURES
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FLASH POINT LEL UEL
None N/A N/A
EXTINGUSING MEDIA
Use agents suitable for surrounding fires.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus
(SCBA) and other protective clothing. Hazardous decomposition products
possible (see Section 10). Dike area as run-off may create additional
environmental contamination
UNUSUAL FIRE AND EXPLOSION HAZARDS: Decomposition forms toxic fumes of sodium
oxide. Flammable gas may be produced on contact with metals.
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Section 6 -- ACCIDENTAL RELEASE MEASURES
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Keep people away.
Wear chemical protective clothing. Stop discharge if possible. Isolate and
remove discharged material. Flush and clean area with water
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Section 7 -- HANDLING AND STORAGE
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PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed and
upright when not in use. Store only in polyethylene or glass containers.
DO NOT USE METAL CONTAINERS.
OTHER PRECAUTIONS: Do not permit workers to handle without proper
training or proper protective equipment. Store in well-sealed containers,
which are protected from physical damage. Empty containers may contain
residues; treat as if full and observe all product precautions. Do not
reuse container. KEEP OUT OF REACH OF CHILDREN.
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Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
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RESPIRATORY PROTECTION (SPECIFY TYPE): In confined, poorly ventilated areas,
use NIOSH/MSHA approved self-contained breathing apparatus. None required for
normal use in adequately ventilated areas where TLV is not exceeded.
VENTILATION - LOCAL EXHAUST: Acceptable
SPECIAL: Explosion proof
MECHANICAL (GENERAL): Preferable
OTHER: N/A
PROTECTIVE GLOVES: Rubber or neoprene
EYE PROTECTION: Chemical splash goggles (ANSI Z-87.1 or equivalent)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Coveralls recommended.
WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed
areas thoroughly before eating, drinking, smoking, or leaving work area.
Launder contaminated clothing before reuse.
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Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
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BOILING POINT: >212 F (>100 C) @ 760mm Hg
SPECIFIC GRAVITY (H20 = 1): 1.09
VAPOR PRESSURE (mm Hg): 1 @ 77 F (20 C)
MELTING POINT: N/A
VAPOR DENSITY (AIR = 1): >1
EVAPORATION RATE (ETHYL ACETATE = 1): <1
APPEARANCE/ODOR: Dark Blue or Purple/ Slight Odor
SOLUBILITY IN WATER: Soluble
VOLATILE ORGANIC COMPOUNDS(VOC)Content
(Theoretical Percentage By Weight): 0% or (0 g/L)
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Section 10 -- STABILITY AND REACTIVITY
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STABILITY: Stable
CONDITIONS TO AVOID: Heat, sparks, open flames.
INCOMPATIBILITY (MATERIALS TO AVOID): Acids, flammable liquids, organics,
halogens, metals, nitromethane. When wet, attacks chemically active metals such
as aluminum, tin, lead, and zinc to produce flammable hydrogen gas.
HAZARDOUS DECOMPOSITION PRODUCTS: Decomposition forms toxic fumes of sodium
oxide.
HAZARDOUS POLYMERIZATION: Will not occur.
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Section 11 -- TOXICOLOGY INFORMATION
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CHRONIC HEALTH HAZARDS
No ingredient in this product is an IARC, NTP or OSHA listed carcinogen.
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TOXICOLOGY DATA
Ingredient Name
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Sodium Phosphate
Oral-Rabbit, adult LD50: 3053 mg/kg
Inhalation-Rat LC50: N/D
Sodium Hydroxide
Oral-Rabbit, adult LDLo: 500 mg/kg
Inhalation-Rat LC50: N/D
Sodium Nitrite
Oral-Rabbit, adult LD50: 85 mg/kg
Inhalation-Rat LC50: 5500 mg/m3
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Section 12 -- Ecological Information
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ECOLOGICAL DATA
Ingredient Name
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Sodium Phosphate
Food Chain Concentration Potential N/D
WATERFOWL TOXICITY N/D
BOD N/D
AQUATIC TOXICITY N/D
Sodium Hydroxide
Food Chain Concentration Potential None
WATERFOWL TOXICITY N/D
BOD None
AQUATIC TOXICITY 125 ppm/96 hr/mosquito fish/TLm
Sodium Nitrite
Food Chain Concentration Potential None
WATERFOWL TOXICITY N/A
BOD N/A
AQUATIC TOXICITY 17.1 ppm/24 hr/minnow
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Section 13 -- DISPOSAL CONSIDERATIONS
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Waste Classification: Corrosive(D002)
Disposal Method: Neutralization
RCRA classified hazardous waste. Dispose of absorbed materials and liquid
waste in accordance with all local, state and federal regulations.
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Section 14 -- TRANSPORTATION INFORMATION
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DOT: Corrosive liquid, basic, inorganic, n.o.s. (sodium hydroxide & sodium
nitrite), Class 8, UN3266, PGIII, ERG154
OCEAN (IMDG): Corrosive liquid, basic, inorganic, n.o.s. (sodium hydroxide &
sodium nitrite), Class 8, UN3266, PGIII, IMDG#8147-1 EmS#8-15, MFAG#760
AIR (IATA): Corrosive liquid, basic, inorganic, n.o.s. (sodium hydroxide &
sodium nitrite), Class 8, UN3266, PGIII
WHMIS (CANADA): Class E
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Section 15 -- REGULATORY INFORMATION
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REGULATORY DATA
Ingredient Name
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Sodium Phosphate
SARA 313 No
TSCA Inventory Yes
CERCLA RQ N/A
RCRA Code N/A
Sodium Hydroxide
SARA 313 No
TSCA Inventory Yes
CERCLA RQ 1000 lb.
RCRA Code N/A
Sodium Nitrite
SARA 313 Yes
TSCA Inventory Yes
CERCLA RQ 100 lb.
RCRA Code N/A
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Section 16 -- OTHER INFORMATION
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This document is prepared pursuant to the OSHA Hazard Communication
Standard (29 CFR 1910.1200). The information herein is given in good faith,
but no warranty, expressed or implied is made. Consult RectorSeal for further
information: (713) 263-8001